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Título

H2 production by steam reforming with in situ CO2 capture of biomass-derived bio-oil

Autor Gil Matellanes, María Victoria ; Esteban Díez, Gonzalo ; Pevida García, Covadonga ; Chen, D.; Rubiera González, Fernando
Palabras clave H2 production
Sorption enhanced steam reforming (SESR)
Pd/Ni-Co catalyst;
Biomass
Bio-oil
Fecha de publicación dic-2014
EditorElsevier
Citación Energy Procedia 63: 6815-6823 (2014)
ResumenHigh-purity H2 was produced by the sorption enhanced steam reforming (SESR) of acetic acid, a model compound of bio-oil obtained from biomass fast pyrolysis. A fixed bed reactor comprising two sections with different temperature was used to favor the reforming reaction in the high-temperature section, and the water gas shift (WGS) and the CO2 capture reactions along the low-temperature segment. A Pd/Ni-Co hydrotalcite-like material (HT) was used as catalyst and a CaO-based material as CO2 sorbent. High H2 yield (84.4%), with H2 purity of 99.8%, was obtained at atmospheric pressure and 600 °C in the above section of the bed followed by a bed temperature of 500 °C at the bottom part. A null CO concentration was achieved, while the CH4 and CO2 contents showed very low values (0.15% and 0.02%, respectively).
Descripción 12th International Conference on Greenhouse Gas Control Technologies, GHGT-12
Versión del editorhttp://dx.doi.org/10.1016/j.egypro.2014.11.715
URI http://hdl.handle.net/10261/109671
DOI10.1016/j.egypro.2014.11.715
ISSN1876-6102
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