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Title

The role of boson-fermion statistics on the Raman spectra of Br2(X) in helium clusters

AuthorsLópez-Durán, David ; Lara Castells, María Pilar de ; Delgado Barrio, Gerardo ; Villarreal, Pablo ; Paola, C. di; Gianturco, Franco A.; Jellinek, J.
Issue Date29-Jul-2004
PublisherAmerican Physical Society
CitationPhysical Review Letters, 93 (5): 053401 (2004)
AbstractThe role played by the bosonic or fermionic character of He atoms surrounding a Br2 X molecule is analyzed through vibrotational Raman spectra simulations. Quantum chemistry-type calculations reveal the spin multiplicity to be chiefly responsible for the drastic difference observed by Grebenev et al. [Science 279, 2083 (1998)] in the rotational structure of molecules embedded in helium droplets.
Description4 pags. ; 1 fig. ; 1 tab. ; PACS numbers: 36.40.Mr, 31.15.Ar, 33.20.Fb, 33.80.Gj
Publisher version (URL)http://dx.doi.org/10.1103/PhysRevLett.93.053401
URIhttp://hdl.handle.net/10261/108768
DOI10.1103/PhysRevLett.93.053401
ISSN0031-9007
Appears in Collections:(CFMAC-IFF) Artículos
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