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Title

Stereospecific carbene polymerisation with oxygenated Rh(diene) species

AuthorsWalters, Annemarie J. C.; Troeppner, Oliver; Ivanović-Burmazović, Ivana; Tejel, Cristina ; Río, M. Pilar del ; Reek, Joost N. H.; Bruin, Bas de
KeywordsDiazo compounds
Oxidation
Polymerization
Rhodium
Issue Date2012
PublisherWiley-VCH
CitationAngewandte Chemie - International Edition 51(21): 5157-5161 (2012)
AbstractBreath-taking activation: Stereoregular carbene polymerization proceeds via cationic [(allyl)RhIII–polymeryl]+ species. These are most efficiently generated by oxygenation of the [(diene)RhI] precatalysts, which involves an unusual rearrangement of 2-rhodaoxetane intermediates. This discovery gives detailed insight in the reaction mechanism.
Publisher version (URL)http://dx.doi.org/10.1002/anie.201200069
URIhttp://hdl.handle.net/10261/108700
DOI10.1002/anie.201200069
Identifiersdoi: 10.1002/anie.201200069
issn: 1433-7851
e-issn: 1521-3773
Appears in Collections:(ISQCH) Artículos
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