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Sulfoxide-directed enantioselective synthesis of functionalized tetrahydropyridines

AuthorsFernández de la Pradilla, Roberto ; Simal, Carmen; Bates, Robert H.; Viso, Alma ; Infantes, L.
Issue Date2013
PublisherAmerican Chemical Society
CitationOrganic Letters 15: 4936-4939 (2013)
AbstractThe highly selective base-promoted cyclization of enantiopure sulfinyl dienamines provides stereodefined sulfinyl 1,2,3,6-tetrahydropyridines (dr up to 99:1). Subsequent sigmatropic rearrangement affords tetrahydropyridin-3-ols in good yields and selectivities.
Identifiersdoi: 10.1021/ol402141d
issn: 1523-7060
e-issn: 1523-7052
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