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Boryl-assisted hydrogenolysis of a nickel–methyl bond

AuthorsCurado, Natalia ; Maya, Celia ; López-Serrano, Joaquín ; Rodríguez, Amor
Issue Date2014
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications, 50: 15718-15721 (2014)
AbstractA stable Nickel(II) methyl complex containing a diphosphinoboryl (PBP) pincer ligand is described. Mechanistic studies on the hydrogenolysis of the Ni-Me bond suggest a metal ligand cooperation mechanism that involves the intermediacy of a - B‒H Ni(0) species that further undergoes B‒H oxidative addition to form a Ni(II) hydride complex.
Publisher version (URL)http://dx.doi.org/ 10.1039/C4CC07616H
Appears in Collections:(IIQ) Artículos
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