High-resolution stimulated Raman spectroscopy and analysis of the v2 and v3 bands of C2H4

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Título :	High-resolution stimulated Raman spectroscopy and analysis of the v2 and v3 bands of C2H4
Autor :	Ballandras, A. Cirtog, M.; Logroño, M.A.; Bourgeois, M.-T.; Rotger, M.; Bermejo, Dionisio ; Martínez, Raúl Z. ; Doménech, José Luis ; Boudon, Vincent
Palabras clave :	Tensorial High-resolution stimulated Raman spectroscopy formalism Global analysis Modeling Ethylene
Fecha de publicación :	2013
Editor:	John Wiley & Sons
Citación :	Journal of Raman Spectroscopy 44 (2013)
Resumen:	The high-resolution stimulated Raman spectra of the ¿2 and ¿3 bands of C2H4 have been recorded and analyzed separately by means of the tensorial formalism developed in Dijon and Reims for X2Y4 asymmetric-top molecules. For the ¿2 band, a total of 191 lines were assigned and fitted. We obtained a global root mean square deviation of 1.86¿×¿10¿¿3¿cm¿¿1. For the ¿3 band analyzed in interaction with the ¿6 infrared band, a total of 185 lines were assigned and fitted. We obtained a global root mean square deviation of 1.29¿×¿10¿¿3¿cm¿¿1. Both analyses lead to very satisfactory synthetic spectra. Copyright © 2013 John Wiley & Sons, Ltd.
URI :	http://hdl.handle.net/10261/103802
DOI:	10.1002/jrs.4328
Identificadores:	doi: 10.1002/jrs.4328 issn: 1097-4555
Aparece en las colecciones:	(CFMAC-IEM) Artículos

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