English   español  
Por favor, use este identificador para citar o enlazar a este item: http://hdl.handle.net/10261/102906
Compartir / Impacto:
Estadísticas
Add this article to your Mendeley library MendeleyBASE
Citado 12 veces en Web of Knowledge®  |  Ver citas en Google académico
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar otros formatos: Exportar EndNote (RIS)Exportar EndNote (RIS)Exportar EndNote (RIS)
Título

Controlling spin transition in one-dimensional coordination polymers through polymorphism

Autor Novio, Fernando ; Campo, Javier; Ruiz Molina, Daniel
Fecha de publicación 2014
EditorAmerican Chemical Society
Citación Inorganic Chemistry 53(16): 8742-8748 (2014)
ResumenA series of polymer 1 microcrystals with several different morphologies have been systematically synthesized by controlling experimental parameters, namely concentration of reactants, temperature, solvent nature, and the use of surfactants, and their valence tautomerism (VT) has been studied by combined electron microscopy, X-ray diffraction data, and magnetization. Our results indicate that all of them can be grouped exclusively into two different crystalline phases, or a mixture of them, that critically determine the VT process, independent of the morphology and/or dimensions of the crystals. Moreover, a difference in the critical temperature of both phases by more than 50 K allows us to regulate VT. These results head the use of valence tautomeric 1D polymers in devices where strict control and reproducibility of the switching behavior at different length scales and integration procedures is highly required. © 2014 American Chemical Society.
Versión del editorhttp://dx.doi.org/10.1021/ic5013928
URI http://hdl.handle.net/10261/102906
DOI10.1021/ic5013928
Identificadoresdoi: 10.1021/ic5013928
e-issn: 1520-510X
issn: 0020-1669
Aparece en las colecciones: (ICMA) Artículos
(CIN2) Artículos
Ficheros en este ítem:
Fichero Descripción Tamaño Formato  
accesoRestringido.pdf15,38 kBAdobe PDFVista previa
Visualizar/Abrir
Mostrar el registro completo
 



NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.