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http://hdl.handle.net/10261/102642
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dc.contributor.author | Oteyza, Dimas G. de | - |
dc.contributor.author | García-Lastra, J. M. | - |
dc.contributor.author | Goiri, Elizabeth | - |
dc.contributor.author | El-Sayed, Afaf | - |
dc.contributor.author | Wakayama, Yutaka | - |
dc.contributor.author | Ortega, J. Enrique | - |
dc.date.accessioned | 2014-09-29T12:40:26Z | - |
dc.date.available | 2014-09-29T12:40:26Z | - |
dc.date.issued | 2014 | - |
dc.identifier | doi: 10.1021/jp506151j | - |
dc.identifier | e-issn: 1932-7455 | - |
dc.identifier | issn: 1932-7447 | - |
dc.identifier.citation | Journal of Physical Chemistry C 118(32): 18626-18630 (2014) | - |
dc.identifier.uri | http://hdl.handle.net/10261/102642 | - |
dc.description.abstract | We report a didactic and simple example of the subtleness in the balance of intermolecular and molecule-substrate interactions and its effect on molecular self-assembly. The study is performed on two closely related molecular blends of copper phthalocyanines and pentacene, in each of which one of the two molecules is fluorinated. Reversing the fluorination brings about changes in the intermolecular hydrogen bonds, as well as in the interactions with the substrate. As a result, on Au(100) substrates one blend assembles into a crystalline structure, whereas the other, displaying weaker intermolecular interactions and a larger corrugation in the molecule-substrate interaction potential, results in a disordered layer. However, the difference between the two blend's structures vanishes when substrates with less corrugated interaction potentials are used. © 2014 American Chemical Society. | - |
dc.description.sponsorship | This work was supported by the Spanish Grant Nos. MAT2010-21156-C03- and PIB2010US-00652 and the Basque Government Grant No. IT-621-13. J.M.G.-L. acknowledges support from the Spanish Ministry of Economy and Competitiveness under projects FIS2012-30996 and FIS2010-21282-C02-01 and from the ReLiable project funded by the Danish Council for Strategic Research-Programme Commission on Sustainable Energy and Environment (project no. 11-116792). | - |
dc.publisher | American Chemical Society | - |
dc.rights | closedAccess | - |
dc.title | Asymmetric response toward molecular fluorination in binary copper-phthalocyanine/pentacene assemblies | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1021/jp506151j | - |
dc.date.updated | 2014-09-29T12:40:26Z | - |
dc.description.version | Peer Reviewed | - |
dc.language.rfc3066 | eng | - |
dc.contributor.funder | Eusko Jaurlaritza | - |
dc.contributor.funder | Ministerio de Economía y Competitividad (España) | - |
dc.contributor.funder | Danish Council for Strategic Research | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003329 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003086 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.fulltext | No Fulltext | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | none | - |
item.openairetype | artículo | - |
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