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dc.contributor.authorPérez-Baena, Irma-
dc.contributor.authorBarroso-Bujans, Fabienne-
dc.contributor.authorGasser, Urs-
dc.contributor.authorArbe, Arantxa-
dc.contributor.authorMoreno Segurado, Ángel J.-
dc.contributor.authorColmenero de León, Juan-
dc.contributor.authorPomposo, José A.-
dc.date.accessioned2014-09-15T13:00:55Z-
dc.date.available2014-09-15T13:00:55Z-
dc.date.issued2013-
dc.identifierdoi: 10.1021/mz4003744-
dc.identifiere-issn: 2161-1653-
dc.identifier.citationACS Macro Letters 2(9): 775-779 (2013)-
dc.identifier.urihttp://hdl.handle.net/10261/102114-
dc.description.abstractThe development of simple, efficient, and robust strategies affording the facile construction of biomimetic organocatalytic nano-objects is currently a subject of great interest. Herein, a new pathway to artificial organocatalysts based on partially collapsed individual soft nano-objects displaying useful and diverse biomimetic catalytic functions is reported. Single-chain polymer nanoparticles endowed with enzyme-mimetic activity synthesized following this new route display (i) a relatively extended morphology under good solvent conditions, as revealed by small angle neutron scattering and coarse-grained molecular dynamics simulation results, (ii) multiple, compartmentalized, and accessible catalytic sites in which borane catalytic units are retained via B···O interactions, and (iii) unprecedented reductase and polymerase enzyme-mimetic properties. © 2013 American Chemical Society.-
dc.description.sponsorshipFinancial support from the projects MAT2012-31088 (MINECO) and IT-654-13 (GV) is acknowledged. I. P.-B. acknowledges CSIC for her JAE-PREDOC grant. This work is based on has been supported by the European Commission under the 7th Framework Programme through the 'Research Infrastructures' action of the 'Capacities' Programme, NMI3-II Grant number 283883.-
dc.publisherAmerican Chemical Society-
dc.relationinfo:eu-repo/grantAgreement/EC/FP7/283883-
dc.relation.isversionofPostprint-
dc.rightsopenAccess-
dc.titleEndowing single-chain polymer nanoparticles with enzyme-mimetic activity-
dc.typeartículo-
dc.identifier.doi10.1021/mz4003744-
dc.relation.publisherversionhttp://dx.doi.org/10.1021/mz4003744-
dc.date.updated2014-09-15T13:00:56Z-
dc.description.versionPeer Reviewed-
dc.language.rfc3066eng-
dc.contributor.funderEuropean Commission-
dc.contributor.funderMinisterio de Economía y Competitividad (España)-
dc.contributor.funderEusko Jaurlaritza-
dc.contributor.funderConsejo Superior de Investigaciones Científicas (España)-
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003339es_ES
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