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Title

Synthetic control to achieve Lanthanide(III)/Pyrimidine-4,6-dicarboxylate compounds by preventing oxalate formation: Structural, magnetic, and luminescent properties

AuthorsCepeda, Javier; Balda, Rolindes ; Castillo, Óscar; Fernández, Joaquín
Issue Date2012
PublisherAmerican Chemical Society
CitationInorganic Chemistry 51(14): 7875-7888 (2012)
AbstractThe control over the synthesis conditions (temperature, pH, and atmosphere) to avoid the oxalate formation has allowed obtaining two crystalline architectures in the lanthanide/pyrimidine-4,6-dicarboxylate system. The structural diversity has been rationalized based on the combined effect of the Ln(III) size, the ligand steric hindrance and the reaction temperature employed during the hydrothermal synthesis. The magnetic and luminescence properties of these compounds have also been accomplished.
URIhttp://hdl.handle.net/10261/101688
DOI10.1021/ic3009392
Identifiersdoi: 10.1021/ic3009392
issn: 0020-1669
e-issn: 1520-510X
Appears in Collections:(CFM) Artículos
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