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Título: | Hemilability of P(X)N-type ligands (X = O, N–H): rollover cyclometalation and benzene C–H activation from (P(X)N)PtMe2 complexes |
Autor: | Scheuermann, Margaret L.; Grice, Kyle A.; Ruppel, Matthew J.; Roselló-Merino, Marta CSIC; Kaminsky, Werner; Goldberg, Karen I. | Fecha de publicación: | 2014 | Editor: | Royal Society of Chemistry (UK) | Citación: | Dalton Transactions, 43 :12018 (2014) | Resumen: | The thermolyses of (tBuP(O)N)PtMe2 (1, tBuP(O)N = (di-tert-butylphosphinito)pyridine) and (tBuP(N–H)N)PtMe2 (3, tBuP(N–H)N = (di-tert-butylphosphino)-2-aminopyridine) in benzene-d6 were investigated. With (tBuP(O) N)PtMe2, the product of a rollover cyclometalation of the pyridyl ring was observed in 80% yield along with formation of CH4. In contrast, thermolysis of (tBuP(N–H)N)PtMe2 resulted in competing rollover cyclometalation and intermolecular benzene C–H activation with production of a mixture of CH4 and CH3D | Versión del editor: | http://dx.doi.org/10.1039/c4dt01143k | URI: | http://hdl.handle.net/10261/101022 | DOI: | 10.1039/c4dt01143k |
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