2024-03-29T08:46:07Zhttp://digital.csic.es/dspace-oai/requestoai:digital.csic.es:10261/439332018-10-17T09:20:02Zcom_10261_78com_10261_3col_10261_331
Epoxy-polystyrene-silica sol–gel membranes with high proton conductivity by combination of sulfonation and tungstophosphoric acid doping
Mosa Ruiz, Jadra
Durán, Alicia
Aparicio, Mario
PEMFC
Sol–gel
New hybrid electrolytes based on 2-allylphenol (AP), (3-glycidoxypropyl) trimethoxysilane (GPTMS) and
tetraethoxysilane (TEOS) have been synthesized by sol–gel method and organic polymerisation. Proton
conductivity has been endowed on the base of three strategies: a high concentration of hydroxyl
groups from the inorganic component, SO3
− groups through sulfonation of phenyl rings, and incorporation
of tungstophosphoric acid (PWA). The system AP–GPTMS–TEOS doped with PWA allows to obtain
homogeneous, flexible, transparent and crack-free membranes after sulfonation of phenyl rings from AP.
Membranes characterization includes degree of sulfonation, ion-exchange capacity, water uptake and
proton conductivity. TGA–DTA analysis shows that the hybrid membranes are thermally stable up to
190 ◦C. Chemical stability of hybrid membrane against sulfonation and doping processes was demonstrated
by FTIR and UV–vis-NIR. The membranes present a high ion-exchange capacity, similar to the
Nafion®, and water absorptions below 10%. Conductivities around 10−3 S/cm have been obtained at 40 ◦C
and 65% relative humidity and 3×10−3 S/m at 110 ◦C and 100% RH. These results show that this new kind
of hybrid membranes possess good mechanical properties, high thermal and oxidative stability and high
proton conductivity, making them an alternative to be used as electrolytes up to 150 ◦C in PEM fuel cells
as well as for lower temperatures and humidity (40 ◦C, 65% RH).
2012-01-03T11:09:59Z
2012-01-03T11:09:59Z
2010
artículo
Journal of Membrane Science 361 (2010) 135–142
http://hdl.handle.net/10261/43933
10.1016/j.memsci.2010.05.063
eng
http://dx.doi.org/10.1016/j.memsci.2010.05.063
openAccess
Elsevier