2024-03-28T14:53:47Zhttp://digital.csic.es/dspace-oai/requestoai:digital.csic.es:10261/974212016-02-17T23:47:49Zcom_10261_38com_10261_5col_10261_291
Kleman, Patryk Artur
González-Liste, Pedro J.
García-Garrido, Sergio E.
Cadierno, Victorio
Pizzano, Antonio
2014-05-29T10:23:12Z
2014-05-29T10:23:12Z
2013
Chemistry - A European Journal 19: 16209- 16212 (2013)
http://hdl.handle.net/10261/97421
10.1002/chem.201303500
Going chiral! Highly enantioselective catalytic hydrogenations of enol esters 1 by using a Rh catalyst bearing a POP ligand are described (see scheme; NBD=norbornadiene). The catalytic system has a broad scope and allows the preparation of a wide range of chiral esters 2 bearing diverse alkyls or a benzyl group with high enantioselectivities. These esters can easily be converted in highly enantioenriched 2-alkanols. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
eng
openAccess
Rhodium
Enantioselectivity
Asymmetric hydrogenation
Alcohols
Esters
Highly enantioselective hydrogenation of 1-alkylvinyl benzoates: A simple, nonenzymatic access to chiral 2-alkanols
artículo