2024-03-29T15:40:37Zhttp://digital.csic.es/dspace-oai/requestoai:digital.csic.es:10261/648642016-02-17T12:17:35Zcom_10261_31com_10261_3col_10261_284
Castarlenas, Ricardo
Esteruelas, Miguel A.
Oñate, Enrique
2013-01-23T12:45:07Z
2013-01-23T12:45:07Z
2005
Organometallics 24(18): 4343-4346 (2005)
http://hdl.handle.net/10261/64864
10.1021/om050569e
The complexes [(η6-p-cymene)OsCl(-CHPh)-(IPr)]OTf (4a; IPr = 1,3-bis(2,6-diisopropylphenyl)-imidazolylidene) and [(η6-p- cymene)OsCl(=CHPh)(IMes)]-OTf (4b; IMes = 1,3-bis(2,4,6-trimethylphenyl) imidazolylidene) have been prepared by reaction of the corresponding 16-electron compounds [η6-p-cymene)OsCl(NHC)JOTf (NHC = IPr (3a), IMes (3b)) with phenyldiazomethane, and their potential as initiators for olefin CM, RCM, and ROMP reactions has been explored. © 2005 American Chemical Society.
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N-heterocyclic carbene-osmium complexes for olefin metathesis reactions
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