2024-03-28T08:55:12Zhttp://digital.csic.es/dspace-oai/requestoai:digital.csic.es:10261/1130952016-10-20T09:28:59Zcom_10261_28457com_10261_3col_10261_28462
Arévalo, Rebeca
Pérez, Julio
Riera, Lucía
2015-03-30T07:36:49Z
2015-03-30T07:36:49Z
2015
Chemistry - A European Journal 21(9): 3546-3549 (2015)
http://hdl.handle.net/10261/113095
10.1002/chem.201406442
http://dx.doi.org/10.13039/501100003329
http://dx.doi.org/10.13039/501100003176
The reaction of fac-[Re(bipy)(CO)3(PMe3)][OTf] (bipy = 2,2′-bipyridine) with KN(SiMe3)2 affords two neutral products: cis,trans-[Re(bipy)(CO)2(CN)(PMe3)], and a thermally unstable compound, which features a new C-C bond between a P-bonded methylene group (from methyl group deprotonation) and the C6 position of bipy. The solid-state structures of more stable 1,2-bis[(2,6-diisopropylphenyl) imino]acenaphthene analogs, resulting from the deprotonation of PMe3, PPhMe2, and PPh2Me ligands, are determined by X-ray diffraction.
eng
closedAccess
Carbonyl complexes
C-C coupling
Phosphane ligands
Rhenium
Bipyridine
Deprotonation of coordinated phosphanes in a rhenium complex: C-C coupling with diimine coligands
artículo