2024-03-29T00:23:46Zhttp://digital.csic.es/dspace-oai/requestoai:digital.csic.es:10261/523422022-06-10T10:36:55Zcom_10261_31com_10261_3col_10261_284
DIGITAL.CSIC
author
Dzik, Wojciech I.
author
Calvo, Sara E.
author
Reek, Joost N. H.
author
Lutz, Martin
author
Ciriano, Miguel A.
author
Tejel, Cristina
author
Hetterscheid, Dennis G. H.
author
Bruin, Bas de
funder
European Commission
funder
University of Amsterdam
funder
Netherlands Organization for Scientific Research
2012-06-27T11:06:57Z
2012-06-27T11:06:57Z
2011
Organometallics 30(3): 372-374 (2011)
http://hdl.handle.net/10261/52342
10.1021/om100981v
http://dx.doi.org/10.13039/501100000780http://dx.doi.org/10.13039/501100001827
The binuclear iridium complex [(cod)(Cl)Ir(bpi)Ir(cod)]PF6 (bpi = (pyridin-2-ylmethyl)(pyridin-2-ylmethylene)amine; cod = 1,5-cyclooctadiene) reveals a noteworthy asymmetric binuclear coordination geometry, wherein the bpi ligand acts as a heteroditopic ligand and has an unusual π-coordinated imine moiety. This species is an effective precatalyst for water oxidation. After a short incubation time the catalyst reveals a turnover frequency of 3400 mol mol-1 s-1 with an overall turnover number >1000. © 2011 American Chemical Society.
eng
openAccess
Binuclear [(cod)(Cl)Ir(bpi)Ir(cod)]+ for Catalytic Water Oxidation
artículo
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URL
https://digital.csic.es/bitstream/10261/52342/4/Water%20Oxidation.pdf
File
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Water Oxidation.pdf
URL
https://digital.csic.es/bitstream/10261/52342/6/Water%20Oxidation.pdf.txt
File
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text/plain
Water Oxidation.pdf.txt