2024-03-29T01:54:36Zhttp://digital.csic.es/dspace-oai/requestoai:digital.csic.es:10261/2197002020-12-12T16:50:12Zcom_10261_38com_10261_5col_10261_291
DIGITAL.CSIC
author
Rios, Pablo
author
RodrÃguez, Amor
author
Conejero, Salvador
2020-09-16T10:00:05Z
2020-09-16T10:00:05Z
2020
Chemical Communications 56: 5333- 5349 (2020)
http://hdl.handle.net/10261/219700
10.1039/d0cc01438a
Platinum complexes have been often considered as the least reactive of the group 10 triad metals. Slow kinetics are behind this lack of reactivity but, still, some industrially relevant catalytic process are dominated by platinum compounds and sometimes different selectivities can be found in comparison to Ni or Pd. Nevertheless, during the last years, it has been reported that the catalytic behaviour of well-defined platinum derivatives can be improved through a judicious choice of their electronic and steric properties, leading to highly electrophilic or low-electron count platinum systems. In this feature article, we highlight some catalytic processes in which well-defined electrophilic platinum complexes or coordinatively unsaturated systems play an important role in their catalytic activity.
openAccess
Enhancing the catalytic properties of well-defined electrophilic platinum complexes
artÃculo
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URL
https://digital.csic.es/bitstream/10261/219700/1/d0cc01438a.pdf
File
MD5
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application/pdf
d0cc01438a.pdf