2024-03-29T09:39:46Zhttp://digital.csic.es/dspace-oai/requestoai:digital.csic.es:10261/2068542021-08-23T11:08:42Zcom_10261_46com_10261_3col_10261_299
DIGITAL.CSIC
author
Salzillo, Tommaso
author
Valle, Raffaele G. Della
author
Venuti, Elisabetta
author
Brillante, Aldo
author
Kociok-Köhn, Gabriele
author
Nuzzo, Daniele Di
author
Masino, Matteo
author
Girlando, Alberto
funder
Università di Bologna
funder
Università degli Studi di Parma
2020-04-07T11:07:48Z
2020-04-07T11:07:48Z
2020-03
Crystals 10(3): 177 (2020)
2073-4352
http://hdl.handle.net/10261/206854
http://dx.doi.org/10.13039/501100004770http://dx.doi.org/10.13039/501100005969
The 3:2 Charge Transfer (CT) co-crystal (Perylene)3(TCNQF1)2 is grown by the Physical Vapor Transport (PVT) method, and characterized structurally and spectroscopically. Infrared analysis of the charge sensitive modes reveals a low degree of charge transfer (less than 0.1) between donor and acceptor molecules. The crystal is isostructural to the other 3:2 CT crystals formed by Perylene with TCNQF2 and TCNQF4, whereas such stoichiometry and packing is not known for the CT crystals with non-fluorinated TCNQ. The analysis of the isostructural family of 3:2 Perylene–TCNQFx (x = 1,2,4) co-crystal put in evidence the role of weak F…HC bonding in stabilizing this type of structure
eng
openAccess
Charge transfer crystals
X-ray diffraction
Vibrational spectroscopy
(Perylene)3-(TCNQF1)2: Yet Another Member in the Series of Perylene–TCNQFx Polymorphic Charge Transfer Crystals
artículo
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URL
https://digital.csic.es/bitstream/10261/206854/1/Salzillo_Crystals_2020_editorial.pdf
File
MD5
d3e8b515bbce8e04e2e479afdebd1f62
3255849
application/pdf
Salzillo_Crystals_2020_editorial.pdf