2024-03-29T14:50:15Zhttp://digital.csic.es/dspace-oai/requestoai:digital.csic.es:10261/2019772021-10-27T10:14:44Zcom_10261_31com_10261_3col_10261_284
DIGITAL.CSIC
author
Castillo Vallés, Martín
author
Martínez Bueno, Alejandro
author
Giménez, Raquel
author
Sierra, Teresa
author
Ros, M. Blanca
funder
Ministerio de Economía y Competitividad (España)
funder
Agencia Estatal de Investigación (España)
funder
Ministerio de Ciencia, Innovación y Universidades (España)
funder
Gobierno de Aragón
funder
European Commission
orcid
Castillo Vallés, Martín [0000-0003-4333-6498]
orcid
Martínez Bueno, Alejandro [0000-0003-1807-2072]
orcid
Giménez, Raquel [0000-0002-7854-6316]
orcid
Sierra, Teresa [0000-0001-7091-077X]
orcid
Ros, M. Blanca [0000-0003-4416-1036]
2020-02-26T08:20:28Z
2020-02-26T08:20:28Z
2019
Journal of Materials Chemistry C 7(46): 14454-14470 (2019)
2050-7526
http://hdl.handle.net/10261/201977
10.1039/C9TC04179F
http://dx.doi.org/10.13039/501100010067http://dx.doi.org/10.13039/501100000780http://dx.doi.org/10.13039/501100003329http://dx.doi.org/10.13039/501100011033
With a view to understand the supramolecular assemblies that bring together certain molecules to form innovative functional materials with high-potential applications, the present review focuses on recent examples of molecular structures that are capable of establishing self-assemblies both in bulk and in solvents. This review demonstrates that appropriate rod- and V-shaped, disc-like and star-shaped molecules as well as high-molecular-weight compounds, either dendrimers or polymers, exhibit a dual ability. Intermolecular interactions that provide liquid crystalline order in bulk may also manifest in solution and this can lead to nanomaterials in the form of nanoaggregates. Through bottom-up approaches that involve the self-assembly of molecules driven by hydrogen bonding, π–π stacking, electrostatic or hydrophilic–hydrophobic interactions, appropriate molecules are able to induce a variety of thermotropic mesophases in bulk as well as aggregates with morphologies such as nanoparticles, nanofibers, nanorods or nanotubes in liquid media including systems in which solvents are immobilized and form gel materials. The aim of this work is to highlight the versatility of mesogenic molecules, opening the door to a wide number of possibilities, as well as to help this topic to enter into a more mature period.
eng
openAccess
Beyond liquid crystals: new research trends for mesogenic molecules in liquids
artículo
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URL
https://digital.csic.es/bitstream/10261/201977/3/beyonliquid.pdf
File
MD5
28a187f76d0c4b3c30dc92d4f1557d8a
798663
application/pdf
beyonliquid.pdf