2024-03-29T00:20:10Zhttp://digital.csic.es/dspace-oai/requestoai:digital.csic.es:10261/1348132021-06-14T10:00:59Zcom_10261_84com_10261_5com_10261_89com_10261_3col_10261_337col_10261_342
DIGITAL.CSIC
author
Lobato Ortega, Belén
author
Merino, C.
author
Barranco, Violeta
author
Álvarez Centeno, Teresa
funder
European Commission
2016-07-15T07:33:20Z
2016-07-15T07:33:20Z
2016-06-10
RSC Advances 6(62): 57514-57520 (2016)
http://hdl.handle.net/10261/134813
10.1039/C6RA08865A
2046-2069
http://dx.doi.org/10.13039/501100000780
Helical-ribbon carbon nanofibers produced on an industrial scale were successfully converted in highly functionalized graphene nanoplatelets by using a slight modification of the Hummers oxidation method. The duration of the oxidative process severely affected the interlayer spacing in the resulting nanoplatelets and, consequently, they showed very different exfoliation behavior. Therefore, it was possible to obtain a variety of graphene-related products through their ultrasonication or thermal treatments such as exfoliation-reduction by flash-pyrolysis in air at temperatures between 400 and 1000 °C or standard activation with CO2 at 800 °C. Detailed comparison of the functionalized carbon nanoplatelets, graphene oxides, reduced graphene oxides and activated carbon nanoplatelets reveals the wide spectrum of their properties with specific surface areas in the range of 4–500 m2 g−1, oxygen content from 38 to 5 wt% and different structural ordering. This study also underlines the impact of the structural, textural and chemical changes experienced by the carbon nanofibers along the various processes on the performance as supercapacitor electrodes. This preliminary study, based on cyclic voltammetry in 2 M H2SO4 aqueous electrolyte, is a summary of the strengths and weaknesses of the different graphene-related materials for this application. The helical-ribbon carbon nanofibers displayed only 10 F g−1, the capacitance of the functionalized graphene nanoplatelets greatly rose to 104 F g−1 with clear contributions from pseudocapacitance. Values around 100–120 F g−1 were found for the graphene oxides and activated graphene nanoplatelets although a marked resistive character is detected. Flash-pyrolysis at 1000 °C leads to lower capacitance (79 F g−1) but much quicker charge propagation. Among all these materials, the lower-cost functionalized graphene nanoplatelets displayed the better behavior for aqueous supercapacitors.
eng
openAccess
Large-scale conversion of helical-ribbon carbon nanofibers to a variety of graphene-related materials
artículo
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URL
https://digital.csic.es/bitstream/10261/134813/1/Large-scale%20conversion_Lobato.pdf
File
MD5
07922bb8c0da4359462bc973edc5778d
643231
application/pdf
Large-scale conversion_Lobato.pdf