Title: The High Resolution Infrared Spectrum of HCl+ Authors: Doménech et al. Table: Table 1. Quantum number assignments, observed and calculated wavenumbers and their differences for the v=1-0 band of HCl+ in the ground electronic state ================================================================================ Byte-by-byte Description of file: datafile1.txt -------------------------------------------------------------------------------- Bytes Format Units Label Explanations -------------------------------------------------------------------------------- 1- 2 I2 --- A(Cl) Chlorine mass number 4- 5 I2 --- N' N'=J'-Omega' 7- 8 I2 --- J'+1/2 Upper angular momentum excluding nuclear spin +1/2 10- 10 I1 --- F' Upper angular momentum including nuclear spin +1/2 12- 13 I2 --- N" N"=J"-Omega" 15- 16 I2 --- J"+1/2 Lower angular momentum excluding nuclear spin +1/2 18- 18 I1 --- F" Lower angular momentum including nuclear spin +1/2 20- 22 A3 --- parity Parity 24- 33 F10.5 1/cm obs Observed frequency 35- 37 I3 10+5/cm unc Experimental uncertainty 39- 39 A1 --- flag * marks intensity weighted doublets 41- 50 F10.5 1/cm calc Calculated frequency 52- 59 F8.4 10+5/cm obs-calc Observed-calculated frequency -------------------------------------------------------------------------------- Note (1): N=J-Omega. The $e,f$ parity labelling follows the convention of Brown et al. 1975, JMoSp, 55, 500 . Only transitions with resolved hfs have $F$ quantum numbers assigned. Note (2): Wavenumbers with the same value and flagged with an asterisk have been fitted as an intensity weighted doublet. -------------------------------------------------------------------------------- 35 9 10 10 11 f-f 2337.98554 30 2337.98565 -10.9000 35 9 10 10 11 e-e 2338.14927 30 2338.14982 -54.5000 37 9 9 10 10 e-e 2353.62726 30 2353.62705 20.9000 35 9 9 10 10 e-e 2355.14958 30 2355.14949 8.9000 37 8 8 9 9 e-e 2378.47832 30 2378.47828 4.1000 35 8 8 9 9 f-f 2379.49703 30 2379.49699 3.7000 35 8 8 9 9 e-e 2380.04188 29 2380.04137 -3.4000 37 7 8 8 9 f-f 2385.15702 29 2385.15714 -11.5000 37 7 8 8 9 e-e 2385.26446 29 2385.26438 8.0000 35 7 8 8 9 f-f 2386.73938 29 2386.73949 -10.9000 35 7 8 8 9 e-e 2386.84720 29 2386.84720 0.0000 37 7 7 8 8 f-f 2402.23701 30 2402.23707 -6.0000 37 7 7 8 8 e-e 2402.79351 30 2402.79800 11.3000 35 7 7 8 8 f-f 2403.84008 29 2403.84020 -11.6000 35 7 7 8 8 e-e 2404.40176 29 2404.40173 3.1000 37 6 7 7 8 f-f 2408.71612 29 2408.71628 -15.8000 37 6 7 7 8 e-e 2408.79948 29 2408.79951 -3.0000 35 6 7 7 8 f-f 2410.33649 29 2410.33652 -2.5000 35 6 7 7 8 e-e 2410.42017 29 2410.42011 5.7000 37 6 6 7 7 f-f 2425.99579 30 2425.99596 -17.2000 37 6 6 7 7 e-e 2426.57046 30 2426.57034 12.4000 35 6 6 7 7 f-f 2427.63761 29 2427.63796 -35.1000 35 6 6 7 7 e-e 2428.21322 29 2428.21302 20.4000 37 5 6 6 7 f-f 2431.73935 29 2431.74006 -25.3000 37 5 6 6 7 e-e 2431.80209 29 2431.80221 -11.6000 35 5 6 6 7 f-f 2433.39682 29 2433.39704 -22.0000 35 5 6 6 7 e-e 2433.45941 29 2433.45946 -4.6000 37 5 5 6 6 f-f 2449.19461 30 2449.19486 -25.0000 37 5 5 6 6 e-e 2449.77966 30 2449.77949 17.5000 35 5 5 6 6 f-f 2450.87415 29 2450.87454 -39.2000 35 5 5 6 6 e-e 2451.46023 29 2451.45937 31.8000 37 4 5 5 6 f-f 2454.21624 29 2454.21630 -5.6000 37 4 5 5 6 e-e 2454.26029 29 2454.26037 -8.3000 35 4 5 5 6 f-f 2455.90878 29 2455.90883 -5.4000 35 4 5 5 6 e-e 2455.95312 29 2455.95311 1.4000 37 4 4 5 5 f-f 2471.35783 29 2471.35352 -29.3000 37 4 4 5 5 e-e 2472.41009 29 2472.40972 36.7000 35 4 4 5 5 f-f 2473.53399 29 2473.53425 -25.8000 35 4 4 5 5 e-e 2474.12635 29 2474.12664 16.8000 37 3 4 4 5 f-f 2476.13276 29 2476.13293 -17.4000 37 3 4 4 5 e-e 2476.16199 29 2476.16204 -4.7000 35 3 4 4 5 f-f 2477.85971 29 2477.85982 -11.0000 35 3 4 4 5 e-e 2477.88894 29 2477.88905 -11.2000 37 3 3 4 4 f-f 2493.85010 30 2493.85019 -9.4000 37 3 3 4 4 e-e 2494.44572 30 2494.44545 26.5000 35 3 3 4 4 f-f 2495.60128 29 2495.60147 -19.2000 35 3 3 4 4 e-e 2496.19754 29 2496.19756 -2.1000 37 2 3 3 4 f-f 2497.47797 29 2497.47808 -10.6000 37 2 3 3 4 e-e 2497.49510 29 2497.49532 -22.3000 35 2 3 3 4 f-f 2499.23797 29 2499.23807 -9.5000 35 2 3 3 4 e-e 2499.25516 29 2499.25539 -22.9000 37 2 2 3 3 f-f 2515.27446 90 2515.27564 -17.6000 37 2 2 3 3 e-e 2515.87053 30 2515.87125 -72.0000 35 2 2 3 3 e-e 2517.65721 30 2517.65719 1.9000 37 1 1 1 2 2 2 f-f 2536.06053 30 2536.06064 -10.8000 37 1 1 1 2 2 1 f-f 2536.07194 30 2536.07155 38.5000 37 1 1 2 2 2 3 f-f 2536.08017 30 2536.08039 -21.8000 37 1 1 2 2 2 2 f-f 2536.09722 30 2536.09701 21.3000 37 1 1 2 2 2 1 f-f 2536.10792 36 2536.10792 -0.3000 37 1 1 2 2 2 3 e-e 2536.67608 40 2536.67600 7.9000 35 1 1 1 2 2 2 f-f 2537.87440 30 2537.87442 -1.7000 35 1 1 1 2 2 1 f-f 2537.88770 30 2537.88753 17.4000 35 1 1 2 2 2 3 f-f 2537.89794 30 2537.89354 -19.9000 35 1 1 2 2 2 2 f-f 2537.37839 30 2537.37351 28.2000 35 1 1 2 2 2 1 f-f 2537.93108 40 2537.93122 -13.5000 35 1 1 2 2 2 3 e-e 2538.49530 30 2538.49519 10.6000 35 8 9 8 9 f-e 2543.90798 30 2543.90823 -25.3000 35 8 9 8 9 e-f 2544.52117 30 2544.52074 43.3000 37 7 8 7 8 f-e 2547.47231 30 2547.47272 -40.7000 37 7 8 7 8 e-f 2547.90504 30 2547.90471 33.0000 35 7 8 7 8 f-e 2549.29289 30 2549.29333 -43.7000 35 7 8 7 8 e-f 2549.72760 30 2549.72718 41.5000 37 6 7 6 7 f-e 2552.20628 30 2552.20682 -54.2000 37 6 7 6 7 e-f 2552.49804 30 2552.49787 16.7000 35 6 7 6 7 f-e 2554.03769 29 2554.03350 -40.7000 35 6 7 6 7 e-f 2554.33067 29 2554.33041 25.9000 37 5 6 5 6 f-e 2556.30325 29 2556.30326 -1.2000 37 5 6 5 6 e-f 2556.48721 30 2556.48686 35.0000 35 5 6 5 6 f-e 2558.14354 30 2558.14375 -21.0000 35 5 6 5 6 e-f 2558.32852 29 2558.32355 37.1000 37 4 5 4 5 f-e 2559.76341 300 2559.76356 -15.0000 35 6 6 6 6 e-f 2559.82097 90 2559.35355 82.4000 37 4 5 4 5 e-f 2559.86939 29 2559.86931 8.3000 35 4 5 4 5 f-e 2561.61166 29 2561.61182 -15.6000 35 4 5 4 5 e-f 2561.71830 29 2561.71803 27.4000 37 3 4 3 4 f-e 2562.58950 29 2562.58952 -2.4000 37 3 4 3 4 e-f 2562.64282 29 2562.64274 7.6000 35 3 4 3 4 f-e 2564.44406 30 2564.44411 -5.2000 35 3 4 3 4 e-f 2564.49777 30 2564.49757 20.4000 37 2 3 2 3 f-e 2564.78313 30 2564.78322 -8.5000 37 2 3 2 3 e-f 2564.80462 29 2564.80461 0.7000 35 2 3 2 3 f-e 2566.64268 29 2566.64271 -2.8000 35 2 3 2 3 e-f 2566.66430 29 2566.66420 10.0000 37 1 1 1 1 1 1 e-f 2566.68848 321 * 2566.68698 49.6000 37 1 1 1 1 1 2 e-f 2566.68848 321 * 2566.68922 -74.3000 37 1 1 2 1 1 2 e-f 2566.72444 310 * 2566.72559 -15.2000 37 1 1 2 1 1 1 e-f 2566.72444 310 * 2566.72335 8.7000 35 1 1 1 1 1 2 f-e 2567.39293 30 * 2567.39453 -60.2000 35 1 1 2 1 1 2 f-e 2567.39293 30 * 2567.33784 9.0000 35 1 1 2 1 1 1 f-e 2567.43613 310 * 2567.43553 60.0000 35 1 1 1 1 1 1 f-e 2567.43613 310 * 2567.43822 -9.2000 35 1 1 1 1 1 1 e-f 2568.54858 30 * 2568.54624 33.9000 35 1 1 1 1 1 2 e-f 2568.54858 30 * 2568.54893 -35.3000 35 1 1 2 1 1 2 e-f 2568.53744 30 * 2568.59262 -18.3000 35 1 1 2 1 1 1 e-f 2568.53744 30 * 2568.58993 50.9000 37 2 2 1 1 1 2 f-f 2595.14544 31 2595.14567 -23.0000 37 2 2 2 1 1 2 f-f 2595.15722 50 2595.15659 62.7000 37 2 2 3 1 1 2 f-f 2595.17334 31 2595.17321 12.6000 37 2 2 1 1 1 1 f-f 2595.13575 31 2595.18204 -28.8000 37 2 2 2 1 1 1 f-f 2595.19292 30 2595.19296 -4.1000 35 2 2 3 1 1 2 e-e 2596.50949 30 2596.50965 -16.0000 35 2 2 2 1 1 2 f-f 2597.05898 40 2597.05972 -74.2000 35 2 2 3 1 1 2 f-f 2597.07983 30 2597.07969 13.6000 35 2 2 1 1 1 1 f-f 2597.08989 30 2597.09030 -40.7000 35 2 2 2 1 1 1 f-f 2597.10368 30 2597.10341 26.7000 37 3 3 2 2 e-e 2612.77621 30 2612.77622 -0.5000 37 3 3 2 2 f-f 2613.32739 30 2613.32755 -15.5000 35 3 3 2 2 e-e 2614.70802 304 2614.70850 -48.3000 35 3 3 2 2 f-f 2615.26059 304 2615.26059 -0.2000 37 3 4 2 3 e-e 2629.37646 29 2629.37606 39.9000 37 3 4 2 3 f-f 2629.93114 29 2629.93064 50.4000 37 4 4 3 3 e-e 2630.24871 29 2630.24371 -39.8000 37 4 4 3 3 f-f 2630.78424 30 2630.78370 54.0000 35 3 4 2 3 e-e 2631.87071 30 2631.87025 46.3000 35 3 4 2 3 f-f 2631.88514 29 2631.88488 25.6000 35 4 4 3 3 e-e 2632.20654 29 2632.20613 40.6000 35 4 4 3 3 f-f 2632.74143 29 2632.74143 -0.3000 37 4 5 3 4 e-e 2646.27349 29 2646.27337 12.0000 37 4 5 3 4 f-f 2646.29677 29 2646.29679 -2.2000 37 5 5 4 4 e-e 2647.01358 30 2647.01377 -18.6000 37 5 5 4 4 f-f 2647.53002 29 2647.52961 41.4000 35 4 5 3 4 e-e 2648.24961 29 2648.24956 4.8000 35 4 5 3 4 f-f 2648.27324 29 2648.27309 15.4000 35 5 5 4 4 e-e 2648.99344 29 2648.99386 -41.9000 35 5 5 4 4 f-f 2649.51065 29 2649.51035 30.2000 37 5 6 4 5 e-e 2661.95620 29 2661.95627 -7.1000 37 5 6 4 5 f-f 2661.99004 29 2661.99005 -0.6000 37 6 6 5 5 e-e 2663.05680 29 2663.05700 -19.9000 37 6 6 5 5 f-f 2663.55249 30 2663.55239 10.1000 35 5 6 4 5 e-e 2663.95293 29 2663.95294 -1.1000 35 5 6 4 5 f-f 2663.98692 29 2663.98686 6.0000 35 6 6 5 5 e-e 2665.05808 29 2665.05845 -36.9000 35 6 6 5 5 f-f 2665.55464 29 2665.55442 21.8000 37 6 7 5 6 e-e 2676.95361 29 2676.95362 -0.8000 37 6 7 5 6 f-f 2676.99894 29 2676.99893 1.1000 37 7 7 6 6 e-e 2678.36570 30 2678.36603 -33.0000 37 7 7 6 6 f-f 2678.83952 30 2678.83960 -7.9000 35 6 7 5 6 e-e 2678.96376 29 2678.96921 -4.5000 35 6 7 5 6 f-f 2679.01475 29 2679.01470 4.5000 35 7 7 6 6 e-e 2680.38686 30 2680.38709 -22.7000 35 7 7 6 6 f-f 2680.86136 29 2680.86117 18.8000 37 7 8 6 7 e-e 2637.25430 29 2637.25431 -1.1000 37 7 8 6 7 f-f 2637.31135 29 2637.31202 -21.0000 37 8 8 7 7 e-e 2692.92359 30 2692.92851 -31.6000 35 7 8 6 7 e-e 2693.28730 29 2693.28722 7.7000 35 7 8 6 7 f-f 2693.34524 29 2693.34517 7.1000 37 8 8 7 7 f-f 2693.37932 30 2693.37922 9.8000 35 8 8 7 7 e-e 2694.96717 30 2694.96738 -21.4000 35 8 8 7 7 f-f 2695.41862 29 2695.41854 7.5000 37 8 9 7 8 e-e 2704.84741 29 2704.84732 9.1000 37 8 9 7 8 f-f 2704.37753 30 2704.37797 -44.0000 37 9 9 8 8 e-e 2706.73276 31 2706.73251 24.5000 35 8 9 7 8 e-e 2706.89603 29 2706.89593 10.1000 35 8 9 7 8 f-f 2706.96673 29 2706.96687 -13.5000 37 9 9 8 8 f-f 2707.15972 30 2707.15968 4.2000 35 9 9 8 8 e-e 2708.78713 30 2708.78739 -26.4000 35 9 9 8 8 f-f 2709.21497 29 2709.21493 3.9000 37 9 10 8 9 e-e 2717.72183 29 2717.72169 14.4000 37 9 10 8 9 f-f 2717.80536 29 2717.80551 -15.3000 37 10 10 9 9 e-e 2719.76714 29 2719.76659 55.3000 35 9 10 8 9 e-e 2719.78452 29 2719.78434 18.2000 35 9 10 8 9 f-f 2719.86866 29 2719.86850 16.3000 37 10 10 9 9 f-f 2720.16989 30 2720.16983 6.1000 35 10 10 9 9 e-e 2721.83525 29 2721.83562 -36.7000 35 10 10 9 9 f-f 2722.23924 30 2722.23376 7.8000 37 10 11 9 10 e-e 2729.86710 30 2729.86656 54.0000 37 10 11 9 10 f-f 2729.96335 30 2729.96350 -14.9000 35 10 11 9 10 e-e 2731.94198 29 2731.94156 41.8000 37 11 11 10 10 e-e 2732.02055 30 2732.01971 84.3000 35 10 11 9 10 f-f 2732.03867 29 2732.03888 -20.6000 37 11 11 10 10 f-f 2732.39905 30 2732.39898 7.4000 35 11 11 10 10 e-e 2734.10049 30 2734.10101 -51.5000 35 11 11 10 10 f-f 2734.48023 30 2734.48051 -28.0000