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dc.contributor.authorVries, Richard F. de-
dc.contributor.authorSnejko, Natalia-
dc.contributor.authorIglesias, Marta-
dc.contributor.authorGutiérrez-Puebla, Enrique-
dc.contributor.authorMonge, M. Ángeles-
dc.identifierdoi: 10.1021/cg5002336-
dc.identifiere-issn: 1528-7505-
dc.identifierissn: 1528-7483-
dc.identifier.citationCrystal Growth and Design 14(5): 2516-2521 (2014)-
dc.description.abstractHydrothermally promoted assembly of the multifunctional 3,5-disulfobenzoic acid (3,5-DSB) ligand with the lanthanide series and the 1,10-phenanthroline as a secondary ligand gives rise to the formation of 2D coordination polymers. The isostructural RPF-20-Ln series, with formula [Ln(3,5-DSB)(Phen)(H 2O)]·H2O (Ln = Sm, Eu, Gd, Tb, Dy, Ho, Er, and Yb), present pseudomerohedral twinned crystals. The polymeric network consists of uninodal 2D net (43·63) layers perpendicular to the [010] direction. π-π Stacking interactions between them gives rise to the tridimensional supramolecular framework. The new compounds were tested as catalysts in acid Lewis reactions. A comparative study with other lanthanide MOFs inside the systems Ln/DSB and Ln/DSB/Phen reveals some structural facts that could improve the catalytic behavior of this kind of material. © 2014 American Chemical Society.-
dc.description.sponsorshipR.D. acknowledges a FPI scholarship from Spanish Ministry of Science and Innovation (MICIN) and Fondo Social Europeo from the EU. This work has been supported by the Spanish MCYT Project MAT2010-17571, Consolider-Ingenio CSD2006-2010, MAT2011-29020-C02-02, PHAMA S2009/MAT-1756 Comunidad Autónoma de Madrid.-
dc.publisherAmerican Chemical Society-
dc.titleLn-MOF pseudo-merohedral twinned crystalline family as solvent-free heterogeneous catalysts-
dc.description.versionPeer Reviewed-
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