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Title

A New Methodology for the Rational Design of Molecularly Imprinted Polymers

AuthorsSalvador, Juan Pablo ; Estévez, M. Carmen ; Marco, María Pilar ; Sánchez Baeza, Francisco J.
KeywordsTestosterone
Anabolic steroids
Molecularly imprinted polymers
Rational design.
Issue Date19-Jun-2007
PublisherTaylor & Francis
CitationAnalytical Letters 40(7): 1294-1306 (2007)
AbstractA new rational approach for the preparation of Molecularly Imprinted Polymers (MIPs) based in combined data from computational chemistry models calculations and 1H-NMR experimental data is described. The new method has been checked using the case of MIPs for testosterone. The experimental NMR binding data between potential monomers and the testosterone and the computational models yield information to rationalize the composition of the polymerization mixture (monomer nature, ratio to template, amount of cross-linker and porogen). The designed polymer was prepared and evaluated and the results confirm that the obtained material act as one could be expected for a MIP.
Description13 pages, 4 figures.
Publisher version (URL)http://dx.doi.org/10.1080/00032710701326668
URIhttp://hdl.handle.net/10261/9744
DOI10.1080/00032710701326668
ISSN1532-236X
Appears in Collections:(IQAC) Artículos
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