Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/95035
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Título: | CH4 and CO2 partial pressures influence and deactivation study on the Catalytic Decomposition of Biogas over a Ni catalyst |
Autor: | Llobet, Saúl de CSIC; Pinilla Ibarz, José Luis CSIC ORCID ; Lázaro Elorri, María Jesús CSIC ORCID ; Moliner Álvarez, Rafael CSIC ORCID; Suelves Laiglesia, Isabel CSIC ORCID | Palabras clave: | Catalytic decomposition of biogas CH4-CO2 reaction Ni/Al2O3 catalyst Nanostructured carbon |
Fecha de publicación: | 17-may-2013 | Editor: | Elsevier | Citación: | Fuel 111: 778-783 (2013) | Resumen: | A conceptually similar approach to dry reforming of CH4 (DRM) called Catalytic Decomposition of Biogas (CDB) is proposed. CDB is based on the direct decomposition of CH4 and CO2, which are the most abundant components in biogas (typically with CH4:CO2 molar ratios higher than 1). The main difference between DRM and CDB lies in the desired products obtained in each process. While in DRM carbon formation is not desired and thus avoided, in CDB carbon accumulation in form of filamentous structures is promoted. In this work, the effect of CH4 and CO2 partial pressures on the initial reaction rates of CDB was studied using a Ni/Al2O3 catalyst. Furthermore, a deactivation study was carried out in order to determine the experimental conditions (CH4 and CO2 partial pressures and temperature) at which carbon formation did not deactivate the catalyst. It was proved that after a certain time on stream, CDB can reach the steady state even though the CH4:CO2 molar ratio is higher than one (typical biogas conditions). In addition, temperature increased reaction rates since CDB is an endothermic process, but it had no effect on catalyst deactivation. | Descripción: | 5 pags, 6 figures, 2 tables | Versión del editor: | http://dx.doi.org/10.1016/j.fuel.2013.05.001 | URI: | http://hdl.handle.net/10261/95035 | DOI: | 10.1016/j.fuel.2013.05.001 | Identificadores: | doi: 10.1016/j.fuel.2013.05.001 issn: 0016-2361 |
Aparece en las colecciones: | (ICB) Artículos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
CH4_and_CO2_partial_pressures_influence.pdf | 476,96 kB | Adobe PDF | Visualizar/Abrir |
CORE Recommender
SCOPUSTM
Citations
14
checked on 13-abr-2024
WEB OF SCIENCETM
Citations
14
checked on 29-feb-2024
Page view(s)
397
checked on 18-abr-2024
Download(s)
749
checked on 18-abr-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.