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Title

A quasianalytic kinetic model for nonequilibrium C2H2(1%)/H2/Ar RF plasmas of interest in nanocrystalline diamond growth

AuthorsGordillo Vázquez, Francisco J. ; Albella, J. M.
Keywords[PACS] Plasma reactions (including flowing afterglow and electric discharges)
[PACS] Thermodynamics of plasmas
[PACS] Plasma kinetic equations
Issue Date2002
PublisherInstitute of Physics Publishing
CitationPlasma Sources Science and Technology 11: 498-512 (2002)
AbstractA general quasianalytic space-time averaged kinetic model for studying the nonequilibrium plasma chemistry of medium-pressure (0.1 Torr ≤ p ≤ 0.8 Torr) C2H2(1%)/H2/Ar radiofrequency (RF) (13.56 MHz) plasmas has been built and used for determining simple analytic expressions for the concentrations of some species of interest in nanocrystalline diamond growth. Changes in external processing parameters (particularly initial argon concentration in the feed gas) are found to influence both the electron energy distribution function of the plasma and the different particle population densities. In agreement with recent experimental results, the model predicts an increase of, respectively, the concentration of C2H2 as a function of Ar (up to 90%) and of the concentration of C2(a3 Πu) with growing gas pressure and Ar concentration in the plasma. © 2002 IOP Publishing Ltd
URIhttp://hdl.handle.net/10261/87954
DOI10.1088/0963-0252/11/4/317
Identifiersdoi: 10.1088/0963-0252/11/4/317
issn: 0963-0252
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