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Title

Gas chromatography/mass spectrometry study of enzymatic removal of sterols forming pitch deposits in TCF bleaching of eucalypt kraft pulp.

AuthorsGutiérrez Suárez, Ana ; Río Andrade, José Carlos del ; Ibarra, David ; Rencoret, Jorge ; Romero, Javier; Martínez, Ángel T.
KeywordsEucalyptus
Pulp
Sterols
Laccases
Issue Date27-Aug-2006
CitationIn: Proceedings of the 9th European Workshop on Lignocellulosics and Pulp, Vienna, Austria, August 27-30, Advances in Chemistry and Processing of Lignocellulosics, pp. 278-281.
AbstractIn this work, the suitability of oxidative enzymes in efficiently removing free and conjugated (as esters and glycosides) sterols from Eucalyptus globulus pulp is revealed. The enzymatic treatment was applied as an additional stage of an industrial-type totally chlorine free (TCF) sequence (O-O-Q-PoP) for bleaching eucalypt kraft pulp. The pulp obtained after oxygen delignification was treated with a high-redox potential and thermostable fungal laccase from Pycnoporus cinnabarinus in the presence and absence of 1-hydroxybenzotriazole as a mediator. This pulp was further submitted to chelation and peroxide stages, and compared with a control TCF pulp obtained using chemical reagents. The composition of lipophilic extractives in the pulps and the corresponding liquids was analyzed by gas chromatography and gas chromatography/mass spectrometry. Pulp and papermaking properties of the enzymatically-treated pulps were also evaluated.
URIhttp://hdl.handle.net/10261/86414
Appears in Collections:(IRNAS) Comunicaciones congresos
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