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Title

Ready access to a branched Man 5 oligosaccharide based on regioselective glycosylations of a mannose-tetraol with n-pentenyl orthoesters

AuthorsUriel, Clara ; Gómez, Ana M. ; López, J. Cristobal; Fraser-Reid, B.
Issue Date2012
PublisherRoyal Society of Chemistry (UK)
CitationOrganic and Biomolecular Chemistry 10: 8361- 8370 (2012)
AbstractA branched Man 5 oligosaccharide has been synthesized by sequential regioselective glycosylations on a mannose-tetraol with n-pentenyl orthoester glycosyl-donors promoted by NIS/BF 3·Et 2O, in CH 2Cl 2. An extended n-pentenyl chain was incorporated into the tetraol acceptor to facilitate (a) the solubility of the starting tetraol in CH 2Cl 2, and (b) future manipulations at the reducing end of the Man 5 oligosaccharide. © The Royal Society of Chemistry 2012.
URIhttp://hdl.handle.net/10261/85781
DOI10.1039/c2ob26432c
Identifiersdoi: 10.1039/c2ob26432c
issn: 1477-0520
e-issn: 1477-0539
Appears in Collections:(IQOG) Artículos
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