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Formation and reactivity of new Nicholas-Ferrier pyranosidic cations: Novel access to oxepanes via a 1,6-hydride shift/cyclization sequence

AuthorsGómez, Ana M. ; Lobo, Fernando ; Pérez De Las Vacas, Daniel; Valverde, Serafín ; López, J. Cristobal
Issue Date2010
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications 46: 6159- 6161 (2010)
AbstractPyranosidic allylic (Ferrier) cations that share dicobalt hexacarbonyl propargyl (Nicholas) stabilization at C-1 display a remarkable reactivity leading to either substituted oxepanes or 3-C-branched pyranosides, depending on the substituent at O-6. © 2010 The Royal Society of Chemistry.
Identifiersdoi: 10.1039/c0cc00586j
issn: 1359-7345
e-issn: 1364-548X
Appears in Collections:(IQOG) Artículos
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