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Phase stability and magnetic properties of a new cobalt(II) coordination polymer based on 2-carboxyethylphosphonate and 1,10′-phenanthroline

AuthorsFernández-Zapico, E.; Montejo-Bernardo, J. M. ; Vries, Richard F. de ; García, José R. ; Rodríguez-Fernández, J.; Pedro, Imanol de; Blanco, J. A.
Issue Date2012
CitationJournal of Alloys and Compounds 536(Supl. 1): S507-S510 (2012)
AbstractCo2(HO3PCH2CH2COO)2(C12H8N2)2 has been synthesized from [Co2(HO3PCH2CH2COO)2(C12H8N2)2(μ-OH2)](H2O) by thermal treatment (350 °C) under inert atmosphere (N2). The transformation between the initial compound to a red-pink crystalline solid is mediated by an intermediate blue amorphous material. Co2(HO3PCH2CH2COO)2(C12H8N2)2 is stable in air until 440 °C, showing some trends of being magnetically ordered below 2 K.
Identifiersdoi: 10.1016/j.jallcom.2012.01.012
issn: 0925-8388
e-issn: 1873-4669
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