Enhanced properties of alumina-aluminium titanate composites obtained by spark plasma reaction-sintering of slip cast green bodies

Abstract

Full dense alumina + 40 vol.% aluminium titanate composites were obtained by colloidal filtration and fast reaction-sintering of alumina/titania green bodies by spark plasma sintering at low temperatures (1250-1400 °C). The composites obtained had near-to-theoretical density (>99%) with a bimodal grain size distribution. Phase development analysis demonstrated that aluminium titanate has already formed at 1300 °C. The mechanical properties such as Vickers hardness, flexural strength and fracture toughness of bulk composites are significantly higher than those reported elsewhere, e.g. the composite sintered at 1350 °C show values of about 24 GPa, 424 MPa and 5.4 MPa m 1/2, respectively. The improved mechanical properties of these composites are attributed to the enhanced densification and the finer and more uniform nanostructure achieved by non-conventional fast sintering of slip-cast dense green compacts. © 2012 Elsevier Ltd. All rights reserved.