Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/82448
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Título: | Detection of charred organic matter in soils from a Neolithic settlement in Southern Bavaria, Germany |
Autor: | Schmid, E. M.; Skjemstad, J. O.; Glaser, Bruno; Knicker, Heike CSIC ORCID ; Kögel-Knabner, I. | Palabras clave: | Charred organic carbon Neolithic site 13C NMR Dipolar dephasing NMR Fractionation/high-energy UV photo-oxidation/13C CPMAS NMR spectroscopy Benzenepolycarboxylic acids |
Fecha de publicación: | may-2002 | Editor: | Elsevier | Citación: | Geoderma 107 (1–2): 71–91 (2002) | Resumen: | The amount and chemical structure of the aromatic carbon fraction in archaeological soil materials was investigated. Samples from several Neolithic pits and a ditch from a settlement in southern Germany were analysed together with the surrounding loamy soil. A suite of complementary methods including 13C CPMAS nuclear magnetic resonance (NMR) spectroscopy, dipolar dephasing NMR, combined fractionation/high-energy ultraviolet (UV) photo-oxidation/13C CPMAS NMR spectroscopy and analysis of benzenepolycarboxylic acids (BPCA) were used to investigate the aromatic organic matter composition of the pits. Most of the Neolithic samples gave the highest proportion of NMR spectral intensity in the aryl carbon region with a dominant peak at 130 ppm with very low, if any, signals for substituted aromatic carbons, such as in lignin or other phenols. Between 29% and 77% of soil organic carbon survived UV photo-oxidation, mostly present as aromatic structures. Dipolar dephasing NMR spectroscopy indicated a high degree of condensation for the aromatic rings while scanning electron microscopy showed that the material had a plant-like morphology. The analysis of BPCAs as specific markers provided further evidence for the presence of highly condensed aromatic structures in the organic matter of the Neolithic pits. The evidence therefore that the aromatic carbon is derived from charcoal is strong. This material either originated from soil material that has undergone vegetation fires or from other charred organic material, e.g., residues from Neolithic fire places. | Descripción: | 21 pages, 6 figures, 6 tables, 26 references. | Versión del editor: | http://dx.doi.org/10.1016/S0016-7061(01)00139-2 | URI: | http://hdl.handle.net/10261/82448 | DOI: | 10.1016/S0016-7061(01)00139-2 | ISSN: | 0016-7061 | E-ISSN: | 1872-6259 |
Aparece en las colecciones: | (IRNAS) Artículos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
Acceso restringido Digital CSIC.pdf | 20,83 kB | Adobe PDF | Visualizar/Abrir |
CORE Recommender
SCOPUSTM
Citations
43
checked on 16-abr-2024
WEB OF SCIENCETM
Citations
39
checked on 27-feb-2024
Page view(s)
352
checked on 19-abr-2024
Download(s)
259
checked on 19-abr-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.