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Título: | A model for simultaneous homogeneous and heterogeneous nucleation in the case of slow reaction rate |
Autor: | Nomura, T.; Kousaka, Y.; Alonso Gámez, Manuel CSIC; Fukunaga, M.; Satoh, T. | Fecha de publicación: | 2000 | Editor: | Elsevier | Citación: | Journal of Colloid and Interface Science 221: 195-199 (2000) | Resumen: | Our previous model for simultaneous homogeneous and heterogeneous nucleation, which was successfully tested for silver particle generation by a chemical reduction method, is extended to the case of slow reaction rate. Nucleation in a system containing seed particles in the case where the reaction rate is slow occurs according to the following rule: homogeneous nucleation is predominant when n(p)/n0/* > 1 (n(p) is the seed number concentration, and n0/* the number concentration of homogeneously nucleated particles without seed particles), and heterogeneous nucleation is predominant when n(p)/n0/* < 1. This theoretical prediction is in good agreement with the experimental results obtained for zinc sulfide particles generated by homogeneous precipitation. (C) 2000 Academic Press. | URI: | http://hdl.handle.net/10261/78070 | DOI: | 10.1006/jcis.1999.6588 | Identificadores: | doi: 10.1006/jcis.1999.6588 issn: 0021-9797 |
Aparece en las colecciones: | (CENIM) Artículos |
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