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Title

Spontaneous discrimination of polycyclic aromatic hydrocarbon (PAH) enantiomers on a metal surface

AuthorsOtero, Gonzalo ; Biddau, Giulio; Ozaki, Taisuke; Gómez-Lor, Berta ; Méndez, Javier ; Pérez, Rubén; Martín-Gago, José A.
Issue Date2010
PublisherWiley-VCH
CitationChemistry - A European Journal 16(47): 13920-13924 (2010)
AbstractSurface control: Vacuum deposition of a planarized PAH (C 60H30) on a Pt(111) surface induces chirality caused by the different landing side of the molecule, as shown by in situ STM images. The surface determines the landing side of individual molecules, which present different structural geometries that are shifted by about 35° (see figure). Large-scale calculations explain the atomistic mechanism of the process.
URIhttp://hdl.handle.net/10261/77747
DOI10.1002/chem.201002079
Identifiersdoi: 10.1002/chem.201002079
issn: 0947-6539
e-issn: 1521-3765
Appears in Collections:(ICMM) Artículos
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