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Título: | Chapter 6.3 Triazines, tetrazines and fused ring polyaza systems |
Autor: | Goya, Pilar CSIC ORCID; Gómez de la Oliva, Cristina CSIC ORCID | Fecha de publicación: | 2008 | Citación: | Progress in Heterocyclic Chemistry 19: 414- 435 (2008) | Resumen: | This chapter discusses triazines, tetrazines, and fused-ring polyaza systems. Computational studies of hydrogen bonding complexes between 1,2,3-triazine and water have been carried out. A theoretical study of 1,2,3-triazine in water has been reported. Ternary complexes of europium(III) ions and triazine have been prepared. A complex containing 5,6-diphenyl-(2-pyridyl)-1,2,3-triazine produced efficient electroluminescence. Several 3-mercapto-l,2,4-trizines have been synthesized through the condensation of thiosemicarbazide with diketones under microwave irradiation in a solventless system. In an earlier study, new electrofluorescent switch was prepared with an electroactive fluorescent tetrazine blend of polymer electrolyte. The synthesis and characterization of two new tetrathiafulvalene (TTF) derivatives bearing pyridine-based substitutents and 1,5'-dimethyl-6-oxoverdazyl radicals are described in the chapter. A general and efficient solid-phase synthesis of N-9-substituted 2,8-diamino purines has been described. The key synthetic transformation uses a carbodiimide-mediated cyclization of a thiourea. | URI: | http://hdl.handle.net/10261/77700 | DOI: | 10.1016/S0959-6380(08)80017-7 | Identificadores: | doi: 10.1016/S0959-6380(08)80017-7 issn: 0959-6380 |
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