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| Título: | New seven membered palladacycles: C-Br bond activation of 2-bromo-pyridine derivative by Pd(II) |
Autor: | Nicasio-Collazo, Juan; Álvarez, Eleuterio CSIC ORCID ; Alvarado-Monzón, José C.; Andre-De-Riquer, Gabriel; Jiménez-Halla, J. Oscar C.; León-Rodríguez, Luis M. de; Merino, Gabriel; Morales, Ubaldo; Serrano, Oracio; López, Jorge A. | Fecha de publicación: | 2011 | Editor: | Royal Society of Chemistry (UK) | Citación: | Dalton Transactions 40: 12450- 12453 (2011) | Resumen: | C-Br bond activation followed by a C-C coupling reaction of the 2-bromo-pyridyl unit of [1-phenyl-2-(6-bromopyridin-2-yl)-benzoimidazole] was performed by Pd(CH2CMe2-o-C6H 4)(η4-COD). Two new seven membered palladacycles were obtained. A combined experimental and theoretical DFT study elucidates the mechanism for this reaction. This journal is © The Royal Society of Chemistry. | URI: | http://hdl.handle.net/10261/73642 | DOI: | 10.1039/c1dt11451d | Identificadores: | doi: 10.1039/c1dt11451d issn: 1477-9226 |
| Aparece en las colecciones: | (IIQ) Artículos |
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| 37-2011 IIQ.docx | 97,99 kB | Microsoft Word XML | Visualizar/Abrir |
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