Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/58946
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Título: | Is independent component analysis appropriate for multivariate resolution in analytical chemistry? |
Autor: | Parastar, Hadi; Jalali-Heravi, Mehdi; Tauler, Romà CSIC ORCID | Palabras clave: | Independence Independent component analysis (ICA) Mean-field independent component analysis (MFICA) Multivariate calibration Multivariate classification Multivariate curve resolution (MCR) Multivariate curve resolution-alternating least squares (MCR-ALS) Mutual information (MI) Rotational ambiguity Signal processing |
Fecha de publicación: | 2011 | Editor: | Elsevier | Citación: | TRAC - Trends in Analytical Chemistry 31: 134–143 (2011) | Resumen: | In this article, we examine Independent Component Analysis (ICA) and the concept of Mutual information (MI) as a quantitative measure of independence from the point of view of analytical chemistry. We compare results obtained by different ICA methods with results obtained by Multivariate Curve Resolution Alternating Least Squares (MCR-ALS). These results have shown that, when non-negativity constraints are applied, values of MI increase considerably and the resolved components cannot anymore be considered to be independent (i.e. they can only be considered to be the “least dependent” components). MI values of profiles resolved by MCR-ALS and ICA did not differ significantly when non-negativity constraints were applied. In addition, since data-fitting values were also practically the same in both cases, the solutions provided by them should be considered equivalent from a mathematical point of view and within the region of feasible solutions for the particular set of applied constraints. We therefore conclude that the solutions based only on the independence concept are not necessarily better from the point of view of analytical chemistry than those obtained by other proposed MCR methods. Results obtained in this work also show that ICA can be considered an alternative tool for resolving mixed signals only in a limited number of cases. | Versión del editor: | http://dx.doi.org/10.1016/j.trac.2011.07.010 | URI: | http://hdl.handle.net/10261/58946 | DOI: | 10.1016/j.trac.2011.07.010 | ISSN: | 0165-9936 |
Aparece en las colecciones: | (IDAEA) Artículos |
Mostrar el registro completo
CORE Recommender
SCOPUSTM
Citations
70
checked on 09-abr-2024
WEB OF SCIENCETM
Citations
66
checked on 24-feb-2024
Page view(s)
305
checked on 19-abr-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.