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Closed Access item A miniature and field-applicable multipumping flow analyzer for ammonium monitoring in seawater with fluorescence detection

Authors:Horstkotte, Burkhard
Duarte, Carlos M.
Cerdà, Víctor
Issue Date:2011
Publisher:Elsevier
Citation:Talanta 85: 380- 385 (2011)
Abstract:In this article, a simple, economic, and miniature flow analyzer for ammonium in seawater based on the solenoid micropumps is presented. A single reagent of sodium tetraborate, ortho-phthaldialdehyde (OPA), and sodium sulfite was used and optimized applying the modified SIMPLEX method. A special-made detection cell for fluorescence detection of the reaction product isoindol-1-sulfonat was made and combined with a commercial photomultiplier tube, a long-pass optical filter, and an UV-LED as excitation light source. A LOD down to 13 nmol/L was achieved. The fabrication and application of a miniature reaction coil heating device for reaction rate enhancement is further described. The system featured an injection frequency of 32 h-1 at average standard deviation of 3%. © 2011 Elsevier B.V. All rights reserved.
URI:http://hdl.handle.net/10261/57500
Identifiers:doi: 10.1016/j.talanta.2011.03.078
issn: 0039-9140
Appears in Collections:(IMEDEA) Artículos

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