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http://hdl.handle.net/10261/57454
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Bosch, Paula | - |
dc.contributor.author | Fernández-Arizpe, A. | - |
dc.contributor.author | Mateo, J. L. | - |
dc.contributor.author | Catalina, Fernando | - |
dc.contributor.author | Peinado, Carmen | - |
dc.date.accessioned | 2012-10-08T09:20:46Z | - |
dc.date.available | 2012-10-08T09:20:46Z | - |
dc.date.issued | 2002 | - |
dc.identifier.citation | Journal of Photochemistry and Photobiology A: Chemistry 153 : 135–143 (2002) | es_ES |
dc.identifier.issn | 1010-6030 | - |
dc.identifier.uri | http://hdl.handle.net/10261/57454 | - |
dc.description.abstract | The fluorescence emission of two newfluorescentprobes have been studied in environments of different polarity and viscosity. The probes have been shown to be sensitive to changes in both microviscosity and micropolarity of the surroundings, and their dipolar moments in the excited state have been estimated. They have been used as fluorescent sensors to monitor the photopolymerization reactions of some mono- and di-functional (meth)acrylate monomers, and two commercial photocurable acrylic adhesives. The fluorescence emission band of the probes showed an increase in intensity as the degree of conversion increases, throughout the entire polymerization range in the different systems checked. Their sensitivity have been compared with that of their parent compoundN,N-dimethylamino-bencilidenenmalononitril | es_ES |
dc.description.sponsorship | Thanks are due to European Union Commission (Brite-EuRam Project no. 97-4472) and Comisión Interministerial de Ciencia y Tecnolog´ıa (projects MAT98-0518-CE, MAT98-0518 and MAT2000-1671) for financial support. We thank to Dr. Kurt Dietliker, from Ciba Specialty Chemicals, for providing the photoinitiators, and also to Loctite España for the adhesives | es_ES |
dc.language.iso | eng | es_ES |
dc.rights | closedAccess | es_ES |
dc.subject | Fluorescent probes | es_ES |
dc.subject | Photopolymerization | es_ES |
dc.subject | Microviscosity | es_ES |
dc.subject | Micropolarity | es_ES |
dc.subject | Cure monitoring | es_ES |
dc.title | New fluorescent probes for monitoring the polymerization reaction: p-vinyliden derivatives of N,N-dimethylaminoaryl compounds | es_ES |
dc.type | artículo | es_ES |
dc.identifier.doi | 10.1016/S1010-6030(02)00260-5 | - |
dc.description.peerreviewed | Peer reviewed | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1016/S1010-6030(02)00260-5 | es_ES |
dc.contributor.funder | Comisión Interministerial de Ciencia y Tecnología, CICYT (España) | - |
dc.contributor.funder | European Commission | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100007273 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.cerifentitytype | Publications | - |
item.grantfulltext | none | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | No Fulltext | - |
item.languageiso639-1 | en | - |
item.openairetype | artículo | - |
Aparece en las colecciones: | (IQOG) Artículos (ICTP) Artículos |
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accesoRestringido.pdf | 15,38 kB | Adobe PDF | Visualizar/Abrir |
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