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dc.contributor.authorSchäfer, Sascha-
dc.contributor.authorLuquin, Asunción-
dc.contributor.authorLaguna, Mariano-
dc.date.accessioned2012-09-07T12:22:07Z-
dc.date.available2012-09-07T12:22:07Z-
dc.date.issued2010-05-
dc.identifier.citationPolyhedron 29(8): 1925-1932 (2010)es_ES
dc.identifier.issn0277-5387-
dc.identifier.urihttp://hdl.handle.net/10261/55850-
dc.description8 páginas, 1 figura, 3 tablas, 3 esquemas.-- et al.es_ES
dc.description.abstractThe synthesis of new water soluble N-alkylated derivatives of 1,3,5-triaza-7-phosphaadamantane is presented. The compounds were characterized by means of NMR and IR spectroscopy, mass spectrometry, high resolution mass spectrometry, elemental analysis and X-ray diffraction analysis. The water solubility of these compounds was found to be up to an astonishing 1450 g/L. Several different reactions were performed utilizing these highly interesting compounds as starting materials. It was shown that the substitution of the counter ion can be performed easily. Also transformations at the PTA framework were possible, as shown by an ester cleavage example. To prove that the resulting PTA derivatives are competent as ligands for transition metals, gold(I) complexes were synthesized, using Au(tht)Cl as the metal source. The resulting gold(I) complexes were characterized by 1H NMR and IR spectroscopy, mass and high resolution mass spectrometry or elemental analysis.es_ES
dc.description.sponsorshipThe authors thank the Deutscher Akademischer Austausch Dienst (DAAD) (S.S.) and the Ministerio de Ciencia y Tecnologia for financial support.es_ES
dc.language.isoenges_ES
dc.publisherElsevieres_ES
dc.rightsclosedAccesses_ES
dc.subjectPTAes_ES
dc.subjectPhosphanees_ES
dc.subjectGoldes_ES
dc.subjectComplexes_ES
dc.subjectWater solublees_ES
dc.titleSynthesis, characterization and solubility studies of four new highly water soluble 1,3,5-triaza-7-phosphaadamantane (PTA) salts and their gold(I) complexeses_ES
dc.typeArtículoes_ES
dc.identifier.doi10.1016/j.poly.2010.03.012-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.poly.2010.03.012es_ES
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