Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/53722
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Campo DC | Valor | Lengua/Idioma |
---|---|---|
dc.contributor.author | Royes, Jorge | - |
dc.contributor.author | Custardoy, Laura | - |
dc.contributor.author | Gimeno, Nélida | - |
dc.contributor.author | Oriol, Luis | - |
dc.contributor.author | Tejedor, Rosa M. | - |
dc.contributor.author | Piñol, Milagros | - |
dc.date.accessioned | 2012-07-23T09:19:02Z | - |
dc.date.available | 2012-07-23T09:19:02Z | - |
dc.date.issued | 2012 | - |
dc.identifier | doi: 10.1002/pola.25929 | - |
dc.identifier | issn: 0887-624X | - |
dc.identifier | e-issn: 1099-0518 | - |
dc.identifier.citation | Journal of Polymer Science Part A: Polymer Chemistry 50(8): 1579-1590 (2012) | - |
dc.identifier.uri | http://hdl.handle.net/10261/53722 | - |
dc.description.abstract | Well-defined side-chain liquid crystal azopolymers have been synthesized by click chemistry of poly(propargyl methacrylate) with bifunctional liquid crystalline azides to produce materials with large degrees of functionalization. A polymeric scaffold having pendant alkyne groups was prepared by atom transfer radical polymerization (ATRP) and postfunctionalized by copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) using homo- and heterobifunctional azides. The azides are derivatives of 2,2-bis(hydroxymethyl)propanoic acid (bis-MPA) containing photoresponsive azobenzene and/or liquid crystalline biphenyl moieties. The approach is a convenient alternative to increase the density of functional units in side-chain polymers having moderate polymerization degrees and to modulate the properties of the final material. The article describes the synthesis, characterization, and liquid crystalline properties of the obtained polymers. The effect of the chemical structure and the possible cooperative effects between functional units in the photo-induction of chirality are also evaluated. A switchable photo-transference of chirality from the circularly polarized light (CPL) to material has been achieved. © 2012 Wiley Periodicals, Inc. | - |
dc.description.sponsorship | This work was supported by the Ministerio de Ciencia e Innovación (MICINN), under the project MAT2008-06522- C01, Fondo Europeo de Desarrollo Regional (FEDER), and Gobierno de Aragón funding. N. Gimeno acknowledges CSIC for a JAE-DOC contract. | - |
dc.language.iso | eng | - |
dc.publisher | Wiley-Blackwell | - |
dc.rights | closedAccess | - |
dc.title | Preparation of side-chain liquid crystalline Azopolymers by CuAAC postfunctionalization using bifunctional azides: Induction of chirality using circularly polarized light | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1002/pola.25929 | - |
dc.date.updated | 2012-07-23T09:19:08Z | - |
dc.description.version | Peer Reviewed | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.languageiso639-1 | en | - |
item.fulltext | No Fulltext | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | none | - |
item.openairetype | artículo | - |
Aparece en las colecciones: | (ICMA) Artículos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
accesoRestringido.pdf | 15,38 kB | Adobe PDF | Visualizar/Abrir |
CORE Recommender
SCOPUSTM
Citations
20
checked on 20-abr-2024
WEB OF SCIENCETM
Citations
17
checked on 23-feb-2024
Page view(s)
350
checked on 24-abr-2024
Download(s)
117
checked on 24-abr-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.