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Title

Manganese(III)-mediated cyclodimerization of a hydrazinyl derivative generating an unprecedented 1,2,3,5,6-substituted leuco-verdazyl ring

AuthorsTang, Jinkui; Nayak, Sanjit; Sánchez Costa, J.; Roubeau, Olivier; Teat, Simon J.; Gamez, Patrick; Reedijk, Jan
Issue Date2010
PublisherRoyal Society of Chemistry (UK)
CitationDalton Transactions 39(5): 1361-1365 (2010)
AbstractThe one-pot reaction of Mn(OAc)3 with two equivalents of 6-(pyridine-2-ylhydrazonomethyl)phenol (Hphp) in methanol leads to a unique leuco-verdazyl-type ring. The remarkable cyclodimerization reaction is proposed to involve a number of one-electron oxidative steps mediated by Mn3+ ions, as well as a very uncommon 1,2-radical aryl migration and a nucleophilic attack of the solvent, i.e. methanol.
URIhttp://hdl.handle.net/10261/53122
DOI10.1039/B917410A
Identifiersdoi: 10.1039/B917410A
issn: 1477-9226
e-issn: 1477-9234
Appears in Collections:(ICMA) Artículos
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