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dc.contributor.authorLadrak, T.-
dc.contributor.authorRoubeau, Olivier-
dc.contributor.authorTeat, Simon J.-
dc.contributor.authorGamez, Patrick-
dc.contributor.authorReedijk, Jan-
dc.identifierdoi: 10.1002/ejic.201000378-
dc.identifierissn: 1434-1948-
dc.identifiere-issn: 1099-0682-
dc.identifier.citationEuropean Journal of Inorganic Chemistry 24: 3804-3812 (2010)-
dc.description.abstractTwo new metal-organic frameworks (MOFs), namely [Mn3(atpa) 3(dmf)2] and [Mn2(tpa)2(dmf) 2], were prepared in N,N-dimethylformamide (dmf) from manganese(II) nitrate and two dicarboxylic acid ligands, 2-aminoterephthalic acid (H 2atpa) and terephthalic acid (H2tpa). The molecular structures of these MOFs are compared to two related coordination polymers, namely [Mn3(atpa)2(Hatpa)2] and [Mn 3(tpa)3-(def)2], which were obtained in N,N-diethylformamide (def), to examine the effect of slight ligand or solvent changes on the framework architecture. The four Mn-based MOFs were used as effective Lewis catalysts for the cyanosilylation of acetaldehyde. The four heterogeneous catalytic systems can be re-used without any apparent loss of activity.-
dc.description.sponsorshipSupport from the Graduate Research School Combination “Catalysis” and the European Cooperation in the Field of Science and Technology (COST) program Action D35/0011, the Spanish Consejo Superior de Investigaciones Científicas (CSIC), as well as from the Spanish Ministerio de Ciencia y Innovación, for access to BM16 at the European synchrotron radiation facility (ESRF) through grant number 16-01-723, are acknowledged. The Advanced Light Source is supported by the Director, Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231. -
dc.titleManganese-based metal-organic frameworks as heterogeneous catalysts for the cyanosilylation of acetaldehyde-
dc.description.versionPeer Reviewed-
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