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Closed Access item Influence of the alkaline earth cations on the topology of MII/CuII mixed-metal-organic frameworks (M = Ca, Sr and Ba)

Authors:Ferrando-Soria, J.
Pasán, Jorge
Ruiz-Pérez, Catalina
Fabelo, Oscar
Issue Date:2012
Publisher:Royal Society of Chemistry (Great Britain)
Citation:CrystEngComm 14(3): 761-764 (2012)
Abstract:The use of the mononuclear copper(ii) complex, [Cu II(Me 2pma) 2] 2- (Me 2pma = N-2,6-dimethylphenyloxamate), as a bis(bidentate) metalloligand toward solvated alkaline earth metal cations affords a new series of oxamato-bridged heterobimetallic two-dimensional compounds with mixed square-octagonal [Ca II 2Cu II 3] or square [M II 2Cu II 3] (M = Sr and Ba) layered structures of (4·82) and (44·62) net topologies, respectively. © 2012 The Royal Society of Chemistry.
Identifiers:doi: 10.1039/C1CE06203D
e-issn: 1466-8033
Appears in Collections:(ICMA) Artículos

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