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Closed Access item Dryness sensitive porous 3d-4f metal-organic framework with unusual dynamic behaviour

Authors:Fabelo, Oscar
Cañadillas-Delgado, Laura
Pasán, Jorge
Ruiz-Pérez, Catalina
Issue Date:2012
Publisher:Royal Society of Chemistry (Great Britain)
Citation:CrystEngComm 14(3): 765-767 (2012)
Abstract:A new three-dimensional heteronuclear metal-organic framework has been synthesized using the 1,2,4,5-benzenetetracarboxylate ligand as a linker and Pr(iii)-Cu(ii) dinuclear units as nodes. The resulting structure shows an unexpected dynamic behaviour, where the volume of the crystal structure is shrunk by 11.5% in a dryness atmosphere. © 2012 The Royal Society of Chemistry.
Identifiers:doi: 10.1039/C1CE06210G
e-issn: 1466-8033
Appears in Collections:(ICMA) Artículos

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