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Title: Dryness sensitive porous 3d-4f metal-organic framework with unusual dynamic behaviour
Authors: Fabelo, Oscar, Cañadillas-Delgado, Laura, Pasán, Jorge, Ruiz-Pérez, Catalina
Issue Date: 2012
Publisher: Royal Society of Chemistry (Great Britain)
Abstract: A new three-dimensional heteronuclear metal-organic framework has been synthesized using the 1,2,4,5-benzenetetracarboxylate ligand as a linker and Pr(iii)-Cu(ii) dinuclear units as nodes. The resulting structure shows an unexpected dynamic behaviour, where the volume of the crystal structure is shrunk by 11.5% in a dryness atmosphere. © 2012 The Royal Society of Chemistry.
Identifiers: doi: 10.1039/C1CE06210G
e-issn: 1466-8033
Citation: CrystEngComm 14(3): 765-767 (2012)
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