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Cryogenic magnetocaloric effect in a ferromagnetic molecular dimer

AuthorsEvangelisti, Marco; Roubeau, Olivier; Palacios, Elias; Camón, Agustín; Hooper, Thomas N.; Brechin, Euan K.; Alonso, Juan J.
Issue Date2011
CitationAngewandte Chemie International Edition 50(29): 6606-6609 (2011)
AbstractMolecoolers: An unprecedentedly large cryogenic magnetocaloric effect is observed in gadolinium acetate tetrahydrate (see picture, Gd pink, O red, C gray). The change in its magnetic entropy is ascribed to the high magnetic density combined with dominant ferromagnetism. For the first time in a molecular complex, direct measurements of the magnetocaloric effect corroborate indirect estimates based on heat capacity and magnetization.
DescriptionEl pdf del artículo es la versión post-print.
Publisher version (URL)http://dx.doi.org/10.1002/anie.201102640
Identifiersdoi: 10.1002/anie.201102640
issn: 1433-7851
e-issn: 1521-3773
Appears in Collections:(ICMA) Artículos
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