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dc.contributor.author | Maheswari, P. U. | - |
dc.contributor.author | Teat, Simon J. | - |
dc.contributor.author | Roubeau, Olivier | - |
dc.contributor.author | Reedijk, Jan | - |
dc.date.accessioned | 2012-06-27T11:45:42Z | - |
dc.date.available | 2012-06-27T11:45:42Z | - |
dc.date.issued | 2012 | - |
dc.identifier | doi: 10.1107/S1600536811053451 | - |
dc.identifier | issn: 1600-5368 | - |
dc.identifier.citation | Acta Crystallographica Section E: Structure Reports Online 68(2): m194-m195 (2012) | - |
dc.identifier.uri | http://hdl.handle.net/10261/52349 | - |
dc.description.abstract | The title compound, [Zn2(C42H38N9O3)2(NO3)2]·2CH3CN·0.5H2O, is a bis-phenolate-bridged dinuclear ZnII complex. The asymmetric unit comprises half the zinc complex (the full complex is completed by the application of a centre of inversion), one acetonitrile solvent molecule and a quarter of a water molecule (located on a twofold axis with half-occupancy; H atoms were not located for this molecule). Each triazine-based multidentate ligand uses a phenolate group to bridge ZnII ions, generating a Zn2O2 core. The ZnII ions are five-coordinate, with an additional long Zn-O contact [2.6465 (16) Å], and include a semi-bidentate nitrate ion and a N,N',O-tridentate mode of the ligand in the coordination sphere. Non-coordinating pyridine groups form intramolecular O-HN hydrogen bonds with phenol groups. As suggested by the short O--O donor-acceptor distances between the disordered water molecules and phenol O atoms, these groups also participate in hydrogen bonding. | - |
dc.description.sponsorship | The work described in this paper was supported by the Leiden University Study group WFMO (Werkgroep Fundamenteel Materialen Onderzoek). | - |
dc.language.iso | eng | - |
dc.publisher | International Union of Crystallography | - |
dc.rights | openAccess | - |
dc.title | Bis{l-2-[(4,6-bis{(2-hydroxy-5-methylphenyl)[(pyridin-2-yl)methyl]amino}- 1,3,5-triazin-2-yl)[(pyridin-2-yl-jN)-methyl]amino-jN]-4-methylphenolato- 1:2j2O:O}bis[(nitrato-j2O,O0)zinc]–acetonitrile–water (2/4/1) | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1107/S1600536811053451 | - |
dc.relation.publisherversion | http://dx.doi.org/10.1107/S1600536811053451 | - |
dc.date.updated | 2012-06-27T11:45:43Z | - |
dc.description.version | Peer Reviewed | - |
dc.identifier.pmid | 22346863 | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.grantfulltext | open | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
item.languageiso639-1 | en | - |
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