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Título: | An Oxide-Centered Trinuclear Manganese(III) Compound with a Bulky Phenol-Pyrazolate Ligand |
Autor: | Viciano-Chumillas, M.; Roubeau, Olivier CSIC ORCID; Jongh, L. J. de; Reedijk, Jan | Fecha de publicación: | 2010 | Editor: | Wiley-VCH | Citación: | European Journal of Inorganic Chemistry 6: 947-951 (2010) | Resumen: | A new oxide-centered trinuclear manganese(III) compound with the formula [Mn3(μ3-O)(naphpz)3(O2CMe)(MeOH)2]n (1) {H2naphpz = 2-[1H-pyrazol-5(3)-yl]naphthalen-1-ol} has been synthesized and characterized. Three bulky doubly deprotonated phenol-pyrazole ligands are coordinated to the three manganese(III) ions with a μ3-oxide bridge in the same plane. Methanol and acetate ligands are at the apical positions of the manganese(III) ions. The trinuclear units are bridged by acetate ligands in the anti-anti mode, leading to the formation of 1-D chains. Temperature-dependent magnetic susceptibility studies indicate the presence of overall antiferromagnetic interactions with magnetic exchange constants of J1 ≈ –1.9 and J2 ≈ –5.5 cm–1 and g = 1.91. Weak antiferromagnetic interactions (zJ′ = –0.37 cm–1) between the trinuclear units in the 1-D chain (and between the chains) in compound 1 are present. | URI: | http://hdl.handle.net/10261/52260 | DOI: | 10.1002/ejic.200901007 | Identificadores: | doi: 10.1002/ejic.200901007 issn: 1434-1948 e-issn: 1099-0682 |
Aparece en las colecciones: | (ICMA) Artículos |
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