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dc.contributor.authorYukawa, Yasuhiko-
dc.contributor.authorTeat, Simon J.-
dc.contributor.authorRoubeau, Olivier-
dc.contributor.authorEvangelisti, Marco-
dc.contributor.authorCremades, Eduard-
dc.contributor.authorRuiz, Eliseo-
dc.contributor.authorBarrios, L. A.-
dc.contributor.authorAromí, Guillem-
dc.date.accessioned2012-06-26T10:18:40Z-
dc.date.available2012-06-26T10:18:40Z-
dc.date.issued2011-
dc.identifierdoi: 10.1002/chem.201100769-
dc.identifierissn: 0947-6539-
dc.identifiere-issn: 1521-3765-
dc.identifier.citationChemistry - A European Journal 17(30): 8264-8268 (2011)-
dc.identifier.urihttp://hdl.handle.net/10261/52234-
dc.description.abstractWater is the glue in bridging two [GdNi3] heterometallic fragments to form the new molecular cluster [Et4N][Gd 2Ni6(val)12(MeCN)6(H 2O)3][Gd(NO3)5](ClO 4)5 (1, val= valine anion, see figure), otherwise cemented by amino acid ligands. The shape of the complex cation of 1 resembles an ancient goblet, and its structure holds weak magnetic exchange pathways, as confirmed theoretically and experimentally; this confers the cluster ideal conditions to exhibit good magnetocaloric properties.-
dc.description.sponsorshipThe authors thank the Generalitat de Catalunya for the prize ICREA Academia 2008 (G.A.) and Grant 2009SGR-1459 (E.C. and E.R.) and Spanish MCI through CTQ2009–06959 (G.A., L.B.), MAT2009-13977- C03 (M.E.), and CTQ2008–06670-C02–01 (E.C., ER). The advanced light source (S.J.T.) is supported by the U.S. Department of Energy (DE-AC02–05CH11231).-
dc.language.isoeng-
dc.publisherWiley-VCH-
dc.rightsclosedAccess-
dc.titleA molecular pair of [GdNi3] tetrahedra bridged by water molecules-
dc.typeArtículo-
dc.identifier.doi10.1002/chem.201100769-
dc.relation.publisherversionhttp://dx.doi.org/10.1002/chem.201100769-
dc.date.updated2012-06-26T10:18:41Z-
dc.description.versionPeer Reviewed-
dc.contributor.funderGeneralitat de Catalunya-
dc.contributor.funderMinisterio de Ciencia e Innovación (España)-
dc.contributor.funderDepartment of Energy (US)-
dc.identifier.funderhttp://dx.doi.org/10.13039/501100002809es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100004837es_ES
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