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Título:	A dinuclear gold(I)–silver(I) derivative of 2-cyclopentylidene-2-sulfanylacetic acid and related complexes: synthesis, crystal structures, properties and antitumor activity
Autor:	Laguna, Antonio CSIC ORCID; López-de-Luzuriaga, José M. CSIC ORCID; Monge, Miguel
Fecha de publicación:	2011
Editor:	Wiley-VCH
Citación:	European Journal of Inorganic Chemistry 8: 1322-1332 (2011)
Resumen:	The dinuclear complex [AgAu(PPh3)2cpa] (H2cpa = 2-cyclopentylidene-2-sulfanylacetic acid) was prepared by treating the precursor [Au(PPh3)(Hcpa)] with Ag(PPh3)NO3. The complex was characterised by spectroscopic methods (IR; 1H, 13C, 31P NMR) and mass spectrometry, and the structure was solved by a single-crystal X-ray diffraction study. Luminescence and theoretical studies were carried out, and the antitumor activity was studied in vitro against HeLa-229, A2780 and A2780cis cell lines. The related gold(I)–gold(I), [(AuPPh3)2cpa], and silver(I)–silver(I), [(AgPPh3)2cpa], compounds were also prepared and studied in the solid state and in solution.
Descripción:	et al.
URI:	http://hdl.handle.net/10261/52171
DOI:	10.1002/ejic.201000959
Identificadores:	doi: 10.1002/ejic.201000959 issn: 1434-1948 e-issn: 1099-0682
Aparece en las colecciones:	(ICMA) Artículos

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A dinuclear gold(I)–silver(I) derivative of 2-cyclopentylidene-2-sulfanylacetic acid and related complexes: synthesis, crystal structures, properties and antitumor activity