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Closed Access item 1D and 2D Nuclear magnetic resonance of new silver(I) complexes with achiral and chiral bases as ligands: Crystal structure of [Ag{(S)-(6-CH3)C5H3N-CHN-CH(α-CH 3)C6H5}(PPh3)2](O 3SCF3)

Authors:Cifuentes, Olga
Contreras, Raúl
Laguna, Antonio
Crespo, Olga
Issue Date:2011
Citation:Inorganica Chimica Acta 379(1): 81-89 (2011)
Abstract:Treatment of equimolar amounts of substituted aniline or amine with substituted benzaldehyde leads to the corresponding achiral or chiral Schiff bases (L). The reaction of the bases with [Ag(O3SCF 3)(PPh3)] leads to the preparation of three or four coordinated cationic complexes, [Ag(k1-L)(PPh3) n]+ (n = 1 or 2) which have been characterized by IR, 1D and 2D NMR spectroscopy. The crystal structure of [Ag{(S)-(6-CH3)C5H3N-CHN-CH(α-CH 3)C6H5}(PPh3)2](O 3SCF3) is reported. © 2011 Elsevier B.V. All rights reserved.
Identifiers:doi: 10.1016/j.ica.2011.09.033
issn: 0020-1693
Appears in Collections:(ISQCH) Artículos

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